Phosphorus pentachloride was replaced by thionyl chloride and N, N-dimethyl formamide as chlorinating reagent in chlorination. The effect of reaction temperature and solvent on the yield of Z-isomer and E-isomer was investigated. 氯代时以用亚硫酰氯和N,N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂,并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。
Study on clean production technology of highly purified phosphorus pentachloride 高纯度五氯化磷清洁生产工艺研究